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History[edit]
Sir Isaac Newton's 1687 Principia includes a computation of the speed of sound in air as 979 feet per second (298 m/s). This is too low by about 15%.[3] The discrepancy is due primarily to neglecting the (then unknown) effect of rapidly-fluctuating temperature in a sound wave (in modern terms, sound wave compression and expansion of air is an adiabatic process, not an isothermal process). This error was later rectified by Laplace.[4]
During the 17th century there were several attempts to measure the speed of sound accurately, including attempts by Marin Mersenne in 1630 (1,380 Parisian feet per second), Pierre Gassendi in 1635 (1,473 Parisian feet per second) and Robert Boyle (1,125 Parisian feet per second).[5] In 1709, the Reverend William Derham, Rector of Upminster, published a more accurate measure of the speed of sound, at 1,072 Parisian feet per second.[5] (The Parisian foot was 325 mm. This is longer than the standard "international foot" in common use today, which was officially defined in 1959 as 304.8 mm, making the speed of sound at 20 °C (68 °F) 1,055 Parisian feet per second).
Derham used a telescope from the tower of the church of St. Laurence, Upminster to observe the flash of a distant shotgun being fired, and then measured the time until he heard the gunshot with a half-second pendulum. Measurements were made of gunshots from a number of local landmarks, including North Ockendon church. The distance was known by triangulation, and thus the speed that the sound had travelled was calculated.[6]
Basic concepts[edit]
The transmission of sound can be illustrated by using a model consisting of an array of spherical objects interconnected by springs.
In real material terms, the spheres represent the material's molecules and the springs represent the bonds between them. Sound passes through the system by compressing and expanding the springs, transmitting the acoustic energy to neighboring spheres. This helps transmit the energy in-turn to the neighboring sphere's springs (bonds), and so on.
The speed of sound through the model depends on the stiffness/rigidity of the springs, and the mass of the spheres. As long as the spacing of the spheres remains constant, stiffer springs/bonds transmit energy quicker, while larger spheres transmit the energy slower.
In a real material, the stiffness of the springs is known as the "elastic modulus", and the mass corresponds to the material density. Given that all other things being equal (ceteris paribus), sound will travel slower in spongy materials, and faster in stiffer ones. Effects like dispersion and reflection can also be understood using this model.[citation needed]
For instance, sound will travel 1.59 times faster in nickel than in bronze, due to the greater stiffness of nickel at about the same density. Similarly, sound travels about 1.41 times faster in light hydrogen (protium) gas than in heavy hydrogen (deuterium) gas, since deuterium has similar properties but twice the density. At the same time, "compression-type" sound will travel faster in solids than in liquids, and faster in liquids than in gases, because the solids are more difficult to compress than liquids, while liquids, in turn, are more difficult to compress than gases.
Some textbooks mistakenly state that the speed of sound increases with density. This notion is illustrated by presenting data for three materials, such as air, water, and steel; they each have vastly different compressibility, which more than makes up for the density differences. An illustrative example of the two effects is that sound travels only 4.3 times faster in water than air, despite enormous differences in compressibility of the two media. The reason is that the larger density of water, which works to slow sound in water relative to air, nearly makes up for the compressibility differences in the two media.
A practical example can be observed in Edinburgh when the "One o'Clock Gun" is fired at the eastern end of Edinburgh Castle. Standing at the base of the western end of the Castle Rock, the sound of the Gun can be heard through the rock, slightly before it arrives by the air route, partly delayed by the slightly longer route. It is particularly effective if a multi-gun salute such as for "The Queen's Birthday" is being fired.
Compression and shear waves[edit]
Pressure-pulse or compression-type wave (longitudinal wave) confined to a plane. This is the only type of sound wave that travels in fluids (gases and liquids). A pressure-type wave may also travel in solids, along with other types of waves (transverse waves, see below)
Transverse wave affecting atoms initially confined to a plane. This additional type of sound wave (additional type of elastic wave) travels only in solids, for it requires a sideways shearing motion which is supported by the presence of elasticity in the solid. The sideways shearing motion may take place in any direction which is at right-angle to the direction of wave-travel (only one shear direction is shown here, at right angles to the plane). Furthermore, the right-angle shear direction may change over time and distance, resulting in different types of polarization of shear-waves
In a gas or liquid, sound consists of compression waves. In solids, waves propagate as two different types. A longitudinal wave is associated with compression and decompression in the direction of travel, and is the same process in gases and liquids, with an analogous compression-type wave in solids. Only compression waves are supported in gases and liquids. An additional type of wave, the transverse wave, also called a shear wave, occurs only in solids because only solids support elastic deformations. It is due to elastic deformation of the medium perpendicular to the direction of wave travel; the direction of shear-deformation is called the "polarization" of this type of wave. In general, transverse waves occur as a pair of orthogonal polarizations.
These different waves (compression waves and the different polarizations of shear waves) may have different speeds at the same frequency. Therefore, they arrive at an observer at different times, an extreme example being an earthquake, where sharp compression waves arrive first and rocking transverse waves seconds later.
The speed of a compression wave in a fluid is determined by the medium's compressibility and density. In solids, the compression waves are analogous to those in fluids, depending on compressibility and density, but with the additional factor of shear modulus which affects compression waves due to off-axis elastic energies which are able to influence effective tension and relaxation in a compression. The speed of shear waves, which can occur only in solids, is determined simply by the solid material's shear modulus and density.
Equations[edit]
The speed of sound in mathematical notation is conventionally represented by c, from the Latin celeritas meaning "velocity".
For fluids in general, the speed of sound c is given by the Newton–Laplace equation:
{\displaystyle c={\sqrt {\frac {K_{s}}{\rho }}},}
where
Thus, the speed of sound increases with the stiffness (the resistance of an elastic body to deformation by an applied force) of the material and decreases with an increase in density. For ideal gases, the bulk modulus K is simply the gas pressure multiplied by the dimensionless adiabatic index, which is about 1.4 for air under normal conditions of pressure and temperature.
For general equations of state, if classical mechanics is used, the speed of sound c can be derived[7] as follows:
Consider the sound wave propagating at speed {\displaystyle v}
through a pipe aligned with the {\displaystyle x}
axis and with a cross-sectional area of {\displaystyle A}
. In time interval {\displaystyle dt}
it moves length {\displaystyle dx=v\,dt}
. In steady state, the mass flow rate {\displaystyle {\dot {m}}=\rho vA}
must be the same at the two ends of the tube, therefore the mass flux {\displaystyle j=\rho v}
is constant and {\displaystyle v\,d\rho =-\rho \,dv}
. Per Newton's second law, the pressure-gradient force provides the acceleration:
{\displaystyle {\begin{aligned}{\frac {dv}{dt}}&=-{\frac {1}{\rho }}{\frac {dP}{dx}}\\\rightarrow dP&=(-\rho \,dv){\frac {dx}{dt}}=(v\,d\rho )v\\\rightarrow v^{2}&\equiv c^{2}={\frac {dP}{d\rho }}\end{aligned}}}
And therefore:
{\displaystyle c={\sqrt {\left({\frac {\partial P}{\partial \rho }}\right)_{s}}},}
where
If relativistic effects are important, the speed of sound is calculated from the relativistic Euler equations.
In a non-dispersive medium, the speed of sound is independent of sound frequency, so the speeds of energy transport and sound propagation are the same for all frequencies. Air, a mixture of oxygen and nitrogen, constitutes a non-dispersive medium. However, air does contain a small amount of CO2 which is a dispersive medium, and causes dispersion to air at ultrasonic frequencies (> 28 kHz).[8]
In a dispersive medium, the speed of sound is a function of sound frequency, through the dispersion relation. Each frequency component propagates at its own speed, called the phase velocity, while the energy of the disturbance propagates at the group velocity. The same phenomenon occurs with light waves; see optical dispersion for a description.
Dependence on the properties of the medium[edit]
The speed of sound is variable and depends on the properties of the substance through which the wave is travelling. In solids, the speed of transverse (or shear) waves depends on the shear deformation under shear stress (called the shear modulus), and the density of the medium. Longitudinal (or compression) waves in solids depend on the same two factors with the addition of a dependence on compressibility.
In fluids, only the medium's compressibility and density are the important factors, since fluids do not transmit shear stresses. In heterogeneous fluids, such as a liquid filled with gas bubbles, the density of the liquid and the compressibility of the gas affect the speed of sound in an additive manner, as demonstrated in the hot chocolate effect.
In gases, adiabatic compressibility is directly related to pressure through the heat capacity ratio (adiabatic index), while pressure and density are inversely related to the temperature and molecular weight, thus making only the completely independent properties of temperature and molecular structure important (heat capacity ratio may be determined by temperature and molecular structure, but simple molecular weight is not sufficient to determine it).
Sound propagates faster in low molecular weight gases such as helium than it does in heavier gases such as xenon. For monatomic gases, the speed of sound is about 75% of the mean speed that the atoms move in that gas.
For a given ideal gas the molecular composition is fixed, and thus the speed of sound depends only on its temperature. At a constant temperature, the gas pressure has no effect on the speed of sound, since the density will increase, and since pressure and density (also proportional to pressure) have equal but opposite effects on the speed of sound, and the two contributions cancel out exactly. In a similar way, compression waves in solids depend both on compressibility and density—just as in liquids—but in gases the density contributes to the compressibility in such a way that some part of each attribute factors out, leaving only a dependence on temperature, molecular weight, and heat capacity ratio which can be independently derived from temperature and molecular composition (see derivations below). Thus, for a single given gas (assuming the molecular weight does not change) and over a small temperature range (for which the heat capacity is relatively constant), the speed of sound becomes dependent on only the temperature of the gas.
In non-ideal gas behavior regimen, for which the Van der Waals gas equation would be used, the proportionality is not exact, and there is a slight dependence of sound velocity on the gas pressure.
Humidity has a small but measurable effect on the speed of sound (causing it to increase by about 0.1%–0.6%), because oxygen and nitrogen molecules of the air are replaced by lighter molecules of water. This is a simple mixing effect.
Altitude variation and implications for atmospheric acoustics[edit]
Density and pressure decrease smoothly with altitude, but temperature (red) does not. The speed of sound (blue) depends only on the complicated temperature variation at altitude and can be calculated from it since isolated density and pressure effects on the speed of sound cancel each other. The speed of sound increases with height in two regions of the stratosphere and thermosphere, due to heating effects in these regions.
In the Earth's atmosphere, the chief factor affecting the speed of sound is the temperature. For a given ideal gas with constant heat capacity and composition, the speed of sound is dependent solely upon temperature; see § Details below. In such an ideal case, the effects of decreased density and decreased pressure of altitude cancel each other out, save for the residual effect of temperature.
Since temperature (and thus the speed of sound) decreases with increasing altitude up to 11 km, sound is refracted upward, away from listeners on the ground, creating an acoustic shadow at some distance from the source.[9] The decrease of the speed of sound with height is referred to as a negative sound speed gradient.
However, there are variations in this trend above 11 km. In particular, in the stratosphere above about 20 km, the speed of sound increases with height, due to an increase in temperature from heating within the ozone layer. This produces a positive speed of sound gradient in this region. Still another region of positive gradient occurs at very high altitudes, in the aptly-named thermosphere above 90 km.
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