페니트로티온 C화학적 특성, 용도, 생산화학적 성질

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페니트로티온

카스 번호:122-14-5한글명:페니트로티온동의어(한글):O,O-디메틸-O-4-니트로-M-톨릴포스포로티오에이트;페니트로티온;페나이트로싸이온;O,O-디메틸O-(3-메틸-4-니트로페닐)포스포로티오에이트;O,O-디메틸O-4-니트로-M-톨릴포스포로티오에이트;누바놀;메타티온;엠이피;포스포로티오익산,O,O-디메틸O-(3-메틸-4-니트로페닐)에스테르상품명:Fenitrothion동의어(영문):MEP;Dybar;Fenitrotion;Cyten;oms43;s112a;s5660;Cyfen;cytel;8057hcCBNumber:CB5406210분자식:C9H12NO5PS포뮬러 무게:277.23MOL 파일:122-14-5.molMSDS 파일:SDS

속성

안전

용도

공급 업체 227

페니트로티온 속성

녹는점3.4°C끓는 점140-145°C (0.05 torr)밀도1.3227증기압1.5 x 10-2 Pa (20 °C)굴절률nD25 1.5528인화점>100 °C저장 조건APPROX 4°C용해도클로로포름(용해성), 메탄올(용해성)Specific Gravity1.328 (20℃)수용성0.003g/100mLMerck13,4003BRN8983553LogP3.319 at 25℃CAS 데이터베이스122-14-5(CAS DataBase Reference)NISTFenitrothion(122-14-5)EPAFenitrothion (122-14-5)

안전

• 위험 및 안전 성명
• 위험 및 사전주의 사항 (GHS)

그림문자(GHS):신호 어:유해·위험 문구:예방조치문구:

Danger

페니트로티온 C화학적 특성, 용도, 생산화학적 성질

Pure fenitrothion is a yellowish brown liquid with an unpleasant odor. It is insoluble in water, but readily soluble in common organic solvents, such as acetone, alcohol, benzene, chlorinated hydrocarbons, dichloromethane, 2-propanol, toluene, in ethers, methanol, and xylene. It decomposes explosively. Fenitrothion is a contact insecticide and a selective acaricide of low ovicidal properties. Fenitrothion is effective against a wide range of pests, namely, penetrating, chewing, and sucking insect pests (coffee leaf-miners, locusts, rice stem borers, wheat bugs, fl our beetles, grain beetles, grain weevils) on cereals, cotton, orchard fruits, rice, vegetables, and forests. It may also be used as a fl y, mosquito, and cockroach residual contact spray for farms and public health programs. Fenitrothion is also effective against household insects and all nuisance insects. WHO confi rmed its effectiveness as a vector control agent for malaria. It is extensively used in other countries, including Japan, where parathion has been banned. Occupational workers are exposed to fenitrothion during mixing, loading/transportation, and fi eld applications.용도Fenitrothion is used to control sucking, chewing and boring insects in cereals, soft fruit, tropical fruit, vines, sugar cane, vegetables, turf and forestry. It is also used as a public health insecticide for the control of flies, cockroaches and mosquitoes. Other uses are for the control of stored product pests and locusts.정의ChEBI: An organic thiophosphate that is O,O-dimethyl O-phenyl phosphorothioate substituted by a methyl group at position 3 and a nitro group at position 4.일반 설명Brownish-yellow oil. Used as a selective acaricide and a contact and stomach insecticide against chewing and sucking insects on rice, orchard fruits, vegetables, cereals, cotton and forest. Also used against flies, mosquitoes, and cockroaches.반응 프로필Organophosphates, such as Fenitrothion, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.위험도Cholinesterase inhibitor, use may be restricted.건강위험Fenitrothion is an organophosphate insecticide. It is a highly toxic cholinesterase inhibitor, that acts on the nervous system. Does not cause delayed neurotoxicity and contact produces little irritation.화재위험When heated to decomposition, Fenitrothion emits very toxic fumes of oxides of nitrogen, phosphorus and sulfur. Decomposition at 212-284F produces a mixture of organophosphorus polymers. Unstable in alkaline media. Stable for 2 years if stored at 68-77F. Do not store above 104F.상품명ACCOTHION®; ACEOTHION®; AGRIA 1050®; AGRIYA 1050®; AGROTHION®; AMERICAN CYANAMID CL-47,300®; ARBOGAL®; BAY 41831®; BAYER 41831®; BAYER S 5660®; CEKUTROTHION®; CL 47300®; CP47114®; CYFEN®; CYTEL®; CYTEN®; DICATHION®; DICOFEN®; DYBAR®; EI 47300®; FALITHION®; FENITEX®; FENITOX®; FENSTAN®; FOLETHION®; FOLITHION®; H-35-F 87 (BVM)®; 8057HC®; KALEIT®; KEEN SUPERKILL ANT AND ROACH EXTERMINATOR®; KILLGERM TETRACIDE INSECTICIDAL SPRAY®; KOTION®; MEP (PESTICIDE)®; METATHION®; METATHIONE®; METATION®; MICROMITE®; MONSANTO CP 47114®; NITROPHOS®; NOVATHION®; NUVAND®; NUVANOL®; OLEOSUMIFENE®; OMS 43®; OVADOFOS®; PENNWALT C-4852; PESTROY®; S 112A®; S 5660®; SMT®; SUMITHION®[C]; TURBAIR GRAIN STORAGE INSECTICIDE®; VERTHION®Safety ProfilePoison by ingestion, inhalation, intravenous, and intraperitoneal routes. Moderately toxic by skin contact, intratracheal, and subcutaneous routes. Human systemic effects: coma, diarrhea, dyspnea, gastrointestinal changes, hypermodtty, nausea or vomiting, respiratory depression. Mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, POx, and sox잠재적 노출A potential danger to those involved in the manufacture, formulation, and application of this insecticide. It is a selective acaricide; and a contact and stomach insecticide. Used to control chewing and sucking insects on rice, orchard fruit; vegetables, cereals, cotton, and in forests. Also protects against flies, mosquitoes, and cockroaches신진 대사 경로Fenitrothion is a non-systemic insecticide, the biotransformations and environmental fate of which have been intensively studied and reviewed. Metabolism has been studied in mammals (including humans), birds, fish, crustacea, molluscs, insects, algae, plants and soil. The major routes of biotransformation involve desulfuration to the oxon analogue (fenitrooxon) and hydrolysis to give dimethyl phosphate, O,O-dimethyl phosphorothioate and 3-methyl-4-nitrophenol. Demethylation to give desmethylfenitrothion and its decomposition products, reduction of the nitro group and oxidation of the ring methyl group also occur. Demethylation via glutathione-S-methyl transferases in the liver is a particularly important mechanism in mammals. Reduction of the nitro group to an amino group is important in anaerobic soils and ruminants but this has also been shown to occur in rats, rabbits and humans where it is presumably carried out by bacteria in the gut. Oxidation of the 3-methyl group to hydroxymethyl and carboxylate has been shown to be a degradative route in birds. The major routes of phase II metabolism involve conjugation of 3-methyl-4-nitrophenol to the glucoside in plants and insects, to the sulfate ester in birds and the sulfate ester and glucuronide in mammals.신진 대사The main biotransformation routes involve oxidative desulfuration to the oxon and dearylation to give dimethyl hydrogen phosphate, O,O-dimethyl hydrogen phosphorothioate and 3-methyl-4-nitrophenol. Demethylation dependent on glutathion-S-alkyl transferase is particularly important in mammals.Oxidation of the 3-methyl group to hydroxymethyl and then carboxyl group is also a degradative route. Reduction of the nitro group to an amino group occurs in anaerobic soils and ruminants. The DT50 in soils under upland and submerged conditions were 12–28 and 4–20 d, respectively.운송 방법UN3017 Organophosphorus pesticides, liquid, toxic, flammable, flash point not ,23C, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid. UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required비 호환성Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,strong acids, oxoacids, epoxides. Strong oxidizers may cause release of toxic phosphorus oxides. Organophosphates, in the presence of strong reducing agents such as hydrides, may form highly toxic and flammable phosphine gas. Keep away from alkaline materials폐기물 처리Incineration (for large amounts); alkaline hydrolysis and landfill (for small amounts). In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.페니트로티온 준비 용품 및 원자재원자재

Petroleum crude oil 3-메틸-4-나이트로페놀 O-methyl dichlorothiophosphate 티오포스포릴 염화물 황화디메틸 염화구리(Ⅰ) 염산 질산 m-크레졸 메틸알콜 질산나트륨

준비 용품

펜티온 Malathion+Fenitrothion,E.C. CYANOPHOS 클로르피리포스-메틸 FENITROTHION-O-ANALOG TRIMETHYL THIOPHOSPHATE 론넬

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페니트로티온 공급 업체

글로벌( 227)공급 업체                                             Canada        2                                            China        183                                            France        2                                            Germany        3                                            India        3                                            Japan        6                                            Norway        1                                            Switzerland        1                                            United Kingdom        5                                            United States        21                                            Global        227                                        

공급자전화이메일국가제품 수이점

Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21689	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2989	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22968	58
Shandong chuangyingchemical Co., Ltd.	18853181302	sale@chuangyingchem.com	CHINA	5909	58
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569266 15319487004	1015@dideu.com	China	2263	58

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페니트로티온 관련 검색:

디메틸설페이트 아크릴산메틸 디메틸 카보네이트 클린다마이신 인산염 다이메틸 푸마르산 디메틸디설파이드 다이메틸 설폭사이드 에탄 디메틸 에테르 아스피린 N,N-다이메틸폼아마이드 메틸 파라싸이온(메틸 파라티온) 페니트로티온 Diphenylthiocarbazide Azamethiphos 1-Phenyl-2-nitropropene Dacthal Chlorodimethylphenylsilane